LIGAND DOPING IN FRAMEWORKS

Ligand-Directed Control over Crystal Structures of Inorganic-Organic Frameworks and Formation of Solid Solutions
H H-M Yeung, W Li, P J Saines, T K J Köster, C P Grey and A K Cheetham
Angew. Chem. 19, 5544-5547 (2013)

Inorganic–organic frameworks with 3D Li–O–Li connectivity can form solid solutions through mechanochemical synthesis. High-resolution synchrotron powder X-ray diffraction and cross-polarization solid-state NMR spectroscopy demonstrate complete ligand mixing in the resulting binary and ternary systems (see picture for trends in unit cell volume (V) of the ternary system {Li2(suc)x(mal)y(met)z}n).

Leave a Reply

Fill in your details below or click an icon to log in:

WordPress.com Logo

You are commenting using your WordPress.com account. Log Out / Change )

Twitter picture

You are commenting using your Twitter account. Log Out / Change )

Facebook photo

You are commenting using your Facebook account. Log Out / Change )

Google+ photo

You are commenting using your Google+ account. Log Out / Change )

Connecting to %s